No... not on a DVD that you play in a player attached to a TV... from the user guide PDF
Chapter PlayList support for Blu-ray and web DVDs
Encore CS6 includes new options that provide more flexibility when you play chapter playlists:
Sequential: Play chapter playlists sequentially.
Random: Let the player randomly select a set of chapters to play.
Shuffle: Let the player play all the chapters in any random order.
Encore CS6 provides only the Sequential option for chapter playlists of DVD projects. Find these options in the Chapter PlayList panel. In addition,
Encore CS6 supports Random and Shuffle options for chapter playlists in web DVDs.